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For an overview of Nuka-grenades, see Nuka-grenade.
Nuka grenades are rare and very powerful portable nuclear grenades. The explosion is very similar to the mini nuke and leaves a slight radioactive residue after detonation.
Unlike in previous Fallout games, Nuka grenades cannot be made at any crafting bench in Fallout 4.
One can be found in the Castle armory. Facing the door it is on the top shelf on the far right. Jumping grab is needed, or standing on an adjacent lower shelf, or using the workshop interface by walking back until the player character can target it then using the Store option.